@article {ISI:000366805800006,
	title = {{{\textquoteleft}{\textquoteleft}Fingerprinting{\{}{\textquoteright}{\textquoteright}{\}} tectono-magmatic provenance using trace elements in igneous zircon}},
	journal = {CONTRIBUTIONS TO MINERALOGY AND PETROLOGY},
	volume = {170},
	number = {5-6},
	year = {2015},
	month = {dec},
	type = {Article},
	abstract = {Over 5300 recent SHRIMP-RG analyses of trace elements (TE) in igneous zircon have been compiled and classified based on their original tectono-magmatic setting to empirically evaluate {\textquoteleft}{\textquoteleft}geochemical fingerprints{\{}{\textquoteright}{\textquoteright}{\}} unique to those settings. Immobile element geochemical fingerprints used for lavas are applied with the same rational to zircon, including consideration of mineral competition on zircon TE ratios, and new criteria for distinguishing mid-ocean ridge (MOR), magmatic arc, and ocean island (and other plume-influenced) settings are proposed. The elemental ratios in zircon effective for fingerprinting tectono-magmatic provenance are systematically related to lava composition from equivalent settings. Existing discrimination diagrams using zircon U/Yb versus Hf or Y do not distinguish TE-enriched ocean island settings (i.e., Iceland, Hawaii) from magmatic arc settings. However, bivariate diagrams with combined cation ratios involving U-Nb-Sc-Yb-Gd-Ce provide a more complete distinction of zircon from these settings. On diagrams of U/Yb versus Nb/Yb, most MOR, ocean island, and kimberlite zircon define a broad {\textquoteleft}{\textquoteleft}mantle-zircon array{\{}{\textquoteright}{\textquoteright}{\}}; arc zircon defines a parallel array offset to higher U/Yb. Distinctly low U/Yb ratios of MOR zircon (typically {\textless}0.1) mirror their parental magmas and long-term incompatible element depletion of the MORB mantle. Plume-influenced sources are distinguished from MOR by higher U/Yb, U/Nb, Nb/Yb, and Nb/Sc. For zircon with U/Yb {\textgreater}0.1, high Sc/Yb separates arc settings from low-Sc/Yb plume-influenced sources. The slope of scandium enrichment trends in zircon differ between MOR and continental arc settings, likely reflecting the involvement of amphibole during melt differentiation. Scandium is thus also critical for discriminating provenance, but its behavior in zircon probably reflects contrasting melt fractionation trends between tholeiitic and calc-alkaline systems more than compositional differences in primitive magmas sourced at each tectono-magmatic source.},
	keywords = {HOV Alvin (Human Occupied Vehicle), ROV Jason (Remotely Operated Vehicle)},
	issn = {0010-7999},
	doi = {10.1007/s00410-015-1199-3},
	author = {Grimes, C B and Wooden, J L and Cheadle, M J and John, B E}
}
@article {Wanless2011,
	title = {{Volatile abundances and oxygen isotopes in basaltic to dacitic lavas on mid-ocean ridges: The role of assimilation at spreading centers}},
	journal = {Chemical Geology},
	volume = {287},
	number = {1-2},
	year = {2011},
	pages = {54{\textendash}65},
	abstract = {Most geochemical variability in MOR basalts is consistent with low- to moderate-pressure fractional crystallization of various mantle-derived parental melts. However, our geochemical data from MOR high-silica glasses, including new volatile and oxygen isotope data, suggest that assimilation of altered crustal material plays a significant role in the petrogenesis of dacites and may be important in the formation of basaltic lavas at MOR in general. MOR high-silica andesites and dacites from diverse areas show remarkably similar major element trends, incompatible trace element enrichments, and isotopic signatures suggesting similar processes control their chemistry. In particular, very high Cl and elevated H2O concentrations and relatively light oxygen isotope ratios ({\~{}}~5.8{\textperthousand} vs. expected values of {\~{}}~6.8{\textperthousand}) in fresh dacite glasses can be explained by contamination of magmas from a component of ocean crust altered by hydrothermal fluids. Crystallization of silicate phases and Fe-oxides causes an increase in $δ$18O in residual magma, but assimilation of material initially altered at high temperatures results in lower $δ$18O values. The observed geochemical signatures can be explained by extreme fractional crystallization of a MOR basalt parent combined with partial melting and assimilation (AFC) of amphibole-bearing altered oceanic crust. The MOR dacitic lavas do not appear to be simply the extrusive equivalent of oceanic plagiogranites. The combination of partial melting and assimilation produces a distinct geochemical signature that includes higher incompatible trace element abundances and distinct trace element ratios relative to those observed in plagiogranites.},
	keywords = {ROV DSL-120 (Remotely Operated Vehicle), ROV Jason (Remotely Operated Vehicle)},
	issn = {0009-2541},
	doi = {10.1016/j.chemgeo.2011.05.017},
	url = {http://dx.doi.org/10.1016/j.chemgeo.2011.05.017},
	author = {Wanless, V D and Perfit, M R and Ridley, W I and Wallace, P J and Grimes, C B and Klein, E M}
}
